16. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 9 - 9 Revision: 3 – Replaces : 2 P362+P364: Take off contaminated clothing and wash it before reuse. P391: Collect spillage. P501: Dispose of contents in accordance with local, state or national legislation. Acronyms ADR : European Agreement concerning the International Carriage of Dangerous Goods by Road CAS : Chemical Abstracts Service CLP : Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtu res EC : European Community IATA : International Air Transport A ssociation IBC : Intermediate Bulk Container ICAO : Internationa l Civil Aviation Organization IMDG : International Maritime Dangerous Goods LTEL : Long term exposure limit PBT : Persistent, Bioaccumulative and Toxic REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals RID : Regulations concerning the Inter national Carriage of Dangerous Goods by Rail STEL : Short term exposure limit STOT : Specific Target Organ Toxicity UN : United Nations vPvB : very Persistent and very Bioaccumulative Disclaimers Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith, but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose. Gorilla Glue Europe Ltd gives no warranty as to the fitness of the pr oduct for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. Gorilla Glue Europe Ltd accepts no liability for loss or damage (other than that arising fr om death or personal injury caused by defective product, if proved), resulting from reliance on this information. Freedom under Patents, Copyright and Designs cannot be assumed.
7. SAFETY DATA SHEET Date of Issue: 18 - 01 - 202 1 Date of Revision: 12 - 06 - 2 023 Gorilla Epoxy (Hardener) Page: 7 - 7 Revision: 3 – Replaces: 2 H315: Causes skin irritation. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. H412: Harmful to aquatic life with long lasting effects. Precautionary Statement(s) P101: If medical advice is needed, have product container or label at hand. P102: Keep out of re ach of children. P26 1 : Avoid breathing vapours. P264: Wash hands and exposed skin thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/ protective clothing/eye protection/face protection. P302+P352: IF ON SKIN: Wash with plenty of water. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER/docto r. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P362+P364: Take off contami nated clothing and wash it before reuse. P501: Dispose of contents in accordance with local, state or national legislation. Acronyms CAS : Chemical Abstracts Service CLP : Regulation (EC) No 1272/2008 on cl assification, labelling and packaging of substances and mixtures EC : European Community LTEL : Long term exposure limit PBT : Persistent, Bioaccumulative and Toxic REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals STEL : Short term exposure limit STOT : Specific Target Organ Toxicity vPvB : very Persistent and very Bioaccumulative Disclaimers Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith, but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose. Gorilla Glue Europe Ltd gives no warranty as to the fitness of the product for any particu lar purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. Gorilla Glue Europe Ltd accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information. Freedom under Patents, Copyright and Designs cannot be assumed.
4. SAFETY DATA SHEET Date of Issue: 18 - 01 - 202 1 Date of Revision: 12 - 06 - 2 023 Gorilla Epoxy (Hardener) Page: 4 - 7 Revision: 3 – Replaces: 2 Eye Protecti on Wear protective eye glasses for protection against liquid splashes. Skin protection Wear protective clothing and gloves: Impervious gloves (EN 374). Breakthrough time of the glove material: refer to the information provided by the gloves’ produ cer. Respiratory protection Wear suitable respiratory protection. Thermal hazards Not applicable. 8.2.3. Environmental Exposure Controls Avoid release to the environment. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Physical state Colour Liquid. Amber . Odour Characteristic. Melting point/freezing point Initial boiling point and boiling range Flammability Upper/lower flammability or explosive limits Not known. Not known. Not applicable. Not known. Flashpoint Not known. Auto - ignition temperature Decomposition t emperature pH Kinematic v iscosity S olubi li ty Not known. Not known. Not known. Not k nown. Not known. Partition coefficient: n - octanol/water Vapour pressure Density (g/ml) Relative va pour density Particle characteristics Not known. Not known. 1.12 g/cm³ Not known. Not kn own. 9.2 Other information None. SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable under no rmal conditions. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of hazardous reactions No hazardous reactions known if used for its intended purpose. 10.4 Conditions to avoid None anticipated. 10.5 Incompatible materials Not known. 10.6 Hazardous decomposition products No hazardous decomposition products known.
11. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 4 - 9 Revision: 3 – Replaces : 2 bisphenol A 80 - 05 - 7 2 bisphenol A 80 - 05 - 7 2 IOELV, (8.1) Region Source EU EU Occupational Exposure Limits United Kingdom UK Workplace Exposure Limits EH40/2005 (Fourth edition, published 2020) Remark Notes Carc Capable of causing cancer and/or heritable genetic damage. Sk Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. IOELV Indicative Occupational Exposure Limit Values. Skin The possibility of significant uptake through the skin. (8.1) Inhalable fraction. 8.2 Exposure controls 8.2.1. Appropriate engineering controls Ensure adequate ventilation. A washing facility/water for eye and skin c leaning purposes should be present. 8.2.2. Personal protection equipment Eye Protection Wear protective eye glasses for protection against liquid splashes. Skin protection Wear protective clothing and gloves: Impervious gloves (EN 374). Breakthrough time of the glove material: refer to the information provided by the gloves’ producer. Respiratory protection Wear suitable respiratory protection. Thermal hazards Not applicable. 8. 2.3. Environmental Exposure Controls Avoid release to the environment. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Physical state Colour Liquid . Clear Odour Not known. Melting point/freezing point Initial boiling point and boiling range Flammability Upper/lower flammability or explosive limits Not known. Not known. Not known. Not known. Flashpoint >94 °C [Closed cup] Auto - ignition temperature Decomposition temperature pH Kinematic viscosity S olubility Not known. Not known. Not known. Not known. Solubility (Water) : Slightly soluble ( bis - [4 - (2,3 - epoxipropoxi)phenyl]propane ) Solubility (Other) : Not known.
8. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 1 - 9 Revision: 3 – Replaces : 2 ACCORDING TO EC - REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product Name Gorilla Epoxy (Resin) CAS No. Not applicable. EC No. Not applicable. REACH Registration No. Not known. Unique Formula Identifier (UFI) N312 - W00T - Q00C - KE5Q 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified Use(s) Adhesives. Uses Advised Against Not known. 1.3 Details of the supplier of the safety data sheet Manufactur er Company Identification Gorilla Glue Europe Ltd Address of Manufacturer 26 Eaton Avenue Matrix Park Buckshaw Village Chorley Lancashire Postal code PR7 7NA Telephone: 01257 241 319 E - mail Eucustomercare@gorillaglue.com Office hours 08:30 - 17:00 Supplier Company Identification GG Brands Nethe rlands B.V. Address of Supplier Lichttoren 32 5611 BJ Eindhoven Telephone: +31 85 064 4029 E - mail Eucustomercare@gorillaglue.com Office hours 08:30 - 17:00 1.4 Emergency telephone number Supplier Contact : Stuart Shotton Emergency Phone No. +44 (0)843 507 1200 Northern Ireland: NHS Direct Emergency Phone No. Republic of Ireland: +44 111 ( 24 hours) NPIC Ireland Emergency Phone No. +353 (0) 1 809 2166 (8am - 10pm) SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Regulation (EC) No. 1272/2008 (CLP) Skin Irrit. 2 : Causes skin irritation. Skin Sens. 1 : May cause an allergic skin reaction. Eye Irrit. 2 : Causes serious eye irritation. Aquatic Chronic 2 : Toxic to aquatic life with long lasting effects. 2.2 Label elements According to Regulation (EC) No. 1272/2008 (CLP) Product Name Gorilla Epoxy (Resin) Hazard Pictogram(s) GHS07 GHS09
1. SAFETY DATA SHEET Date of Issue: 18 - 01 - 202 1 Date of Revision: 12 - 06 - 2 023 Gorilla Epoxy (Hardener) Page: 1 - 7 Revision: 3 – Replaces: 2 ACCORDING TO EC - REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product Name Gorilla Epoxy (Hardener) CAS No. Not applicable. EC No. Not applicab le. REACH Registration No. Not known. Unique Formula Identifier (UFI) K2Y8 - 80AU - N00J - Y7A8 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified Use(s) Hardener. Uses Advised Against Not known. 1.3 Details of the supplier of the safety data sheet Manufac turer Company Identification Gorilla Glue Europe Ltd Address of Manufacturer 26 Eaton Avenue Matrix Park Buckshaw Village Chorley Lancashire Postal code PR7 7NA Telephone: 01257 241 319 E - mail Eucustomercare@gorillaglue.com Office hours 08:30 - 17:00 Supplier Company Identification GG Brands Netherlands B.V. Address of Supplier Lichttoren 32 5611 BJ Eindhoven Telephone: +31 85 064 4029 E - mail Eucustomercare@gorillaglue.com Office hours 08:30 - 17:00 1.4 Emergency telephone number Supplier Contact : Stuart Shotton Emergency Phone No. +44 (0)843 507 1200 Northern Irela nd: NHS Direct (24 hours) Emergency Phone No. Republic of Ireland: +44 111 NPIC Irela nd Emergency Phone No. +353 (0) 1 809 2166 (8am - 10pm) SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Regulation (EC) No. 1272/2008 (CLP) Skin Irrit. 2 : Causes skin irritation. Skin Sens. 1A : May cause an allergic skin reaction. Eye Dam. 1 : Causes serious eye damage. Aquatic Chronic 3 : Harmful to aquatic life with long lasting effects. 2.2 Label elements According to Regulation (EC) No. 1272/2008 (CLP) Product Name Gorilla Epoxy (Hardener) Hazard Pictogram(s) GHS05 GHS07
3. SAFETY DATA SHEET Date of Issue: 18 - 01 - 202 1 Date of Revision: 12 - 06 - 2 023 Gorilla Epoxy (Hardener) Page: 3 - 7 Revision: 3 – Replaces: 2 Unlikely to be required but if necessary treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable Extinguishing media As appropriate for surrounding fire. Unsuitable extinguishing media Do not use water jet. 5.2 Special hazards arising from the substance or mixture Heating may cause decomposition. 5.3 Advice for firefighters Fire fighters should wear complete protective clothing including self - contained breathing apparatus. Dike fire control water for later disposal. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Wear suitable protective clothing, gloves and eye/face protection. Avoid breathing vapours. Contaminated work clothing should not be allowed out of the workplace. 6.2 Environmental precautio ns Avoid release to the environment. 6.3 Methods and material for containment and cleaning up Adsorb spillag es onto sand, earth or any suitable adsorbent material. 6.4 Reference to other sections See Also Section 8, 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling If medic al advice is needed, have product container or label at hand. Keep out of reach of children. Avoid breathing vapours. Wear protective gloves/protective clothing/eye protection/face protection. Avoid contact with skin and eyes. Wash hands and exposed s kin thoroughly after handling. Take off contaminated clothing and wash it before reuse. Do not eat, drink or smoke at the work place. 7.2 Conditions for safe storage, including any incompatibilities Keep in a cool, dry, well ventilated place. Opened containers should be carefully resealed and stored in an upright position. Storage temperature 2 - 40 °C Storage life Stable under normal conditions. Incompatible materials None known. 7.3 Specific end us e(s) Hardener. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters 8.1.1 Occupational Exposure Limits Occupational Exposure Limits SUBSTANCE. CAS No. LTEL (8 hr TWA ppm) LTEL (8 hr TWA mg/m³) STEL (ppm) STEL (mg/m³) Note 2,6 - di - tert - butyl - p - cresol 128 - 37 - 0 10 Region Source EU EU Occupational Exposure Limits United Kingdom UK Workplace Exposure Limits EH40/2005 (Fourth edition, published 2020) 8.2 Exposure controls 8.2.1. Appropriate engineering controls Ensure adequate ventilation. A washing facility/water for eye and skin cleaning purposes should be present. 8.2.2. Personal protection equipment
13. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 6 - 9 Revision: 3 – Replaces : 2 Toxicity - Terrestrial Compartment Not classified. 12.2 Persistence and degradability The product is not biodegradable. bis - [4 - (2 ,3 - epoxipropoxi)phenyl]propane : Not readily biodegradable. 12.3 Bioaccumulative potential The product has no potential for bioaccumulation. bis - [4 - (2,3 - epoxipropoxi)phenyl]propane : Bioconcentration factor (BCF) : 31 12.4 Mobility in soil The product is predicted to have moderate mobility in soil. 12.5 Results of PBT and vPvB assessment 12.6 Endocrine Disrupt i ng Properties Not classified as PBT or vPvB. Not known. 12. 7 Other adverse effects Not known. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Dispose of empty containers and wa stes safely. Do not reuse empty containers. 13.2 Additional Information Disposal should be in accordance with local, state or national legislation. SECTION 14: TRANSPORT INFORMATION 14.1 UN number UN No. 3082 14.2 UN proper shipping name UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N. O.S. ( bis - [4 - (2,3 - epoxipropoxi)phenyl]propane ) 14.3 Transport hazard class(es) ADR/RID ADR/RID Class 9 ADR Classification Code M6 Special Provisions 274 335 375 601 Limited Quantities 5 L Excepted Quantities E1 Emergency Action Code •3Z Mixed Packing Instructions for Packages P001 IBC03 LP01 R001 Special Packing Provisions for Packages PP1 Mixed Packing Instructions for Packages MP19 Packing Instructions for Portable Tanks T4 Special Provisions for Portable Tanks TP1 TP29 Tank Code for Tanks LGBV Vehicle for Tank Carriage AT ADR Transport Category 3 Special Provisions for Carriage - Packages V12 Special Provisions for Carriage - Loading, Unloading and Handling CV13 ADR HIN 90 IMDG IMDG Class 9
5. SAFETY DATA SHEET Date of Issue: 18 - 01 - 202 1 Date of Revision: 12 - 06 - 2 023 Gorilla Epoxy (Hardener) Page: 5 - 7 Revision: 3 – Replaces: 2 SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity - Ingestion Low oral toxicity. Acute toxicity - Skin Contact Low acute toxicity. Acute toxicity - Inhalation Low acute toxicity. Skin corrosion/irritation Causes skin irritation. No data. Serious eye damage/irritation Causes serious eye damage. No data. Skin sensitization data May cause an allergic skin reaction. No data. Respiratory sensitization data Not classified. Germ cell mutagenicity There is no evidence of mutagenic potential. Carcinogenicity No evidence of carcinogenic effects. Reproductive toxicity No evidence of reproductive effects. Lactation Not classified. STOT - single exposure None anticipated. STOT - repeated expo sure None anticipated. Aspiration hazard Not classified. 11.2 Other information Not known. SECTION 12: ECOLOGICAL INFORMATION 12 .1 Toxicity Harmful to aquatic life with long lasting effects. Toxicity - Aquatic invertebrates No data. Toxicity - Fish No data. Toxicity - Algae No data. To xicity - Sediment Compartment Not classified. Toxicity - Terr estrial Compartment Not classified. 12.2 Persistence and degradability No information on this formulation. 12.3 Bioaccumulative potential No information on this formulation. 12.4 Mobility in soil No information on this formulation. 12.5 Results of PBT and vPvB assessment 12.6 Endocrine Disrupting Properties Not classified as PBT or vPvB. Not known. 12. 7 Other adverse effects Not known. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Dispose of empty containers and wastes safely. Do not reuse empty containers. 13.2 Additional Information Disposal should be in accordance with local, state or national legislation. SECTION 14: TRANSPORT INFORMATION Not classified as hazardous for transport. 14.1 UN number Not applicable 14.2 UN proper shipping name Not applicable 14.3 Transport hazard class(es)
10. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 3 - 9 Revision: 3 – Replaces : 2 Skin Contact Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Wash out mouth with water. If symptoms develop, obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Causes irritation to eyes and skin. May cause an allergic skin react ion. 4.3 Indication of any immediate medical attention and special treatment needed Unlikely to be required but if necessary treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitabl e Extinguishing media As appropriate for surrounding fire. Unsuitable extinguishing media Do not use water jet. 5.2 Special hazards arising from the substance or mixture Decomposes in a fire giving off toxic fumes: Carbon monoxi de, Carbon dioxide , Halogenated compounds 5.3 Advice for firefighters Fire fighters should wear complete protective clothing including self - contained breathing apparatus. Dike fire control water for later disposal. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Avoid breathing vapours. Wear suitable protective clothing, gloves and eye/face protection. Contaminated work clothing should n ot be allowed out of the workplace. 6.2 Environmental precautions Avoid release to the environment. 6.3 Methods and material for containment and cleaning up Adsorb spillages onto sand, earth or any suitable adsorbent material. Colle ct spillage. Transfer to a container for disposal. 6.4 Reference to other sections See Also Section 8, 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling If medical advice is needed, have product container or label at hand. Keep out of reach of children. Wash hands and exposed skin thor oughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing vapours. Avoid contact with skin and eyes. Take off contaminated clothing and wash it before reuse. Do not eat, drink or smoke at the work place. 7.2 Conditions for safe storage, including any incompatibilities Keep in a cool, dry, well ventilated place. Opened containers shoul d be carefully resealed and stored in an upright position. Storage temperature Ambient. Storage life Stable under normal conditions. Incompatible materials Strong oxidising agents , Acids , Alkalis , Amines 7.3 Specific end use(s) Adhes ives. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters 8.1.1 Occupational Exposure Limits Occupational Exposure Limits SUBSTANCE. CAS No. LTEL (8 hr TWA ppm) LTEL (8 hr TWA mg/m³) STEL (ppm) STEL (mg/m³) Note 1 - chloro - 2,3 - epoxypropane 106 - 89 - 8 0.5 1.9 1.5 5.8 Carc Methanol 67 - 56 - 1 200 266 250 333 Sk Methanol 67 - 56 - 1 200 260 IOELV, Skin
14. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 7 - 9 Revision: 3 – Replaces : 2 Special Provisions 274 335 375 601 Limited Quantities 5 L Excepted Qu antities E1 Mixed Packing Instructions for Packages P001 IBC03 LP01 R001 Special Packing Provisions for Packages PP1 Packing Instructions for Portable Tanks T4 Special Provisions for Portable Tanks TP1 TP29 IMDG EMS F - A S - F Stowage and Handling Category A ICAO/IATA IATA Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( bis - [4 - (2,3 - epoxipropoxi)phenyl]propane ) Excepted Quantities E1 Passenger and Cargo Aircraft Limited Quantities Packing Instructions Y964 Pa ssenger and Cargo Aircraft Limited Quantities Max net Qty 30Kg G Passenger and Cargo Aircraft Packing Instructions 964 Passenger and Cargo Aircraft Max net Qty 450L Cargo Aircraft Packing Instructions 964 Cargo Aircraft Max net Qty 450L Special Provisions A97, A158 A197 Emergency Response Guidebook (ERG) Code 9L Labels Labels 9 14.4 Packing group Packing group III 14.5 Environmental hazards Environmental hazards Classified as a Marine Pollutant. 14.6 Special precautions for user Special precautions for user Not known. 14.7 Maritime transport in bulk according to IMO instruments No information available SECTION 15: REGULATORY INFORMATI ON 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture European Regulations - Authorisations and/or Restrictions On Use Candidate List of Substances of Very High Concern for Authorisation bisphenol A (80 - 05 - 7) REACH: ANNEX XIV list of substances subject to authorisation Not listed REACH: Annex XVII Restrictions on the manufact ure, placing on the market and use of certain dangerous substances, mixtures and articles Carcinogens: category 1B (106 - 89 - 8), Toxic to reproduction: category 1B (80 - 05 - 7), bis - [4 - (2,3 - epoxipropoxi)phenyl]p ropane (1675 - 54 - 3), [3 - (2,3 - epoxypropoxy)propyl]trimethoxysilane (2530 - 83 - 8), Methanol (67 - 56 - 1) Community Rolling Action Plan (CoRAP) bis - [4 - (2,3 - epoxipropoxi)phenyl]propane (1675 - 54 - 3), Methanol (67 - 56 - 1), bisphenol A (80 - 05 - 7) Regulation (EC) N° 850/2004 of the European Parliament and of the Council on persistent organic pollutants Not listed Regulation (EC) N° 1005/2009 on substances that deplete the ozone layer Not listed Regulation (EU) N° 649/2012 of the European Parliament and of the Council Not listed
6. SAFETY DATA SHEET Date of Issue: 18 - 01 - 202 1 Date of Revision: 12 - 06 - 2 023 Gorilla Epoxy (Hardener) Page: 6 - 7 Revision: 3 – Replaces: 2 Not ap plicable 14.4 Packing group Not applicable 14.5 Environmental hazards Not classified as a Marine Pollutant. 14.6 Special precautions for user Not known 14.7 Maritime transport in bulk according to IMO instruments Not known SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture European Regulations - Authorisations and/or Restrictions On Use Candidate List of Substances of Very High Concern for Authorisation Not listed REACH: ANNEX XIV list of substances subject to authorisation Not listed REACH: Annex XVII Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Poly[oxy(methyl - 1,2 - ethanediyl)], α - hydro - ω - hydroxy - , ether with 2,2 - bis(hydroxymethyl) - 1,3 - propanediol (4:1), 2 - hydroxy - 3 - mercaptopropyl ether (72244 - 98 - 5), 2,2,4(or 2,4,4) - trimethylhexane - 1,6 - diamine (25513 - 64 - 8), 1,4 - diazabicyclooctane (280 - 57 - 9), 2,6 - di - tert - butyl - p - cresol (128 - 37 - 0) Community Rolling Action Plan (CoRAP) 2,6 - di - tert - butyl - p - cresol (128 - 37 - 0) Regulation (EC) N° 85 0/2004 of the European Parliament and of the Council on persistent organic pollutants Not listed Regulation (EC) N° 1005/2009 on substances that deplete the ozone layer Not listed Regulation (EU) N° 649/2012 of the European Parliament and of the Council concerning the export and import of hazardous chemic als Not listed National regulations Other Not known. 15.2 Chemical Safety Assessment A REACH chemical safety assessment has not been carried out. SECTION 16: OTHER INFORMATION The following sections contain revisions or new statements: 1 - 16 LEGEND Hazard Pictogram(s) GHS05 GHS07 GHS02: GHS: Flame GHS09: GHS: Environment Hazard classification Flam. Sol. 1 : Flammable solid , Category 1 Acute Tox. 4 : Acute toxicity , Category 4 Skin Corr. 1A : Skin corrosion/irritation , Category 1 A Skin Irrit. 2 : Skin corrosion/irritation , Category 2 Skin Sens. 1A : Skin sensitization , Category 1 A Skin Sens. 1B : Skin sensitization , Category 1 B Eye Dam. 1 : Serious eye damage/irritation , Category 1 Aquatic Acute 1 : Hazardous to the aquatic environment , Acute , Category 1 Aquatic Chronic 1 : Hazardous to the aquatic environment , Chro nic , Category 1 Aquatic Chronic 3 : Hazardous to the aquatic environment , Chronic , Category 3 Hazard Statement(s) H228: Flammable solid. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage.
15. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 8 - 9 Revision: 3 – Replaces : 2 concerning the export and import of hazardous chemicals National regulations Other Not known. 15.2 Chemical Safety Assessment A REACH chemical safety assessment has not been carried out. SECTION 16: OTHER INFORMATION The following sections contain revisions or new statements: 1 - 16 LEGEND Hazard Pictogram(s) GHS07 GHS09 GHS02: GHS: Flame GHS05: GHS: Corrosion GHS06: GHS: Skull and crossbones GHS08: GHS: Health hazard Haz ard classification Flam. Liq. 2 : Flammable liquid , Category 2 Flam. Liq. 3 : Flammable liquid , Category 3 Acute Tox. 3 : Acute toxicity , Category 3 Skin Corr. 1B : Skin corrosion/irritation , Category 1 B Skin Irrit. 2 : Skin corrosion/irritation , Category 2 Skin Sens. 1 : Skin sensitization , Category 1 Eye Dam. 1 : Serious eye damage/irritation , Category 1 Eye Irrit. 2 : Serious eye damage/irritation , Category 2 STOT SE 3 : Specific target organ toxicity — single exposure , Category 3 Carc. 1B : Carcinogenicity , Category 1 B Repr. 1B : Reproductive toxicity , Category 1 B STOT SE 1 : Specific target organ toxicity — single exposure , Category 1 Aquatic Chronic 2 : Hazardous to the aquatic environment , Chronic , Category 2 Hazard Statement(s) H225: Highly flammable liquid and vapour. H226: Flammable liquid and vapour. H301: Toxic if swallowed. H311: Toxic in contact with skin. H314: Causes severe skin burns and eye damage. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H319: Causes serious eye irritation. H331: Toxic if inhaled. H335: May cause respiratory irritation. H350: May cause cancer. H360F: May damage fertility. H370: Causes damage to organs. H411: Toxic to aquatic life with long lasting effects. Precautionary Statement(s) P101: If medical advice is needed, ha ve product container or label at hand. P102: Keep out of reach of children. P261: Avoid breathing vapours. P264: Wash hands and exposed skin thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P302+P352: IF ON SKIN: Wash with plenty of water. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Co ntinue rinsing. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P337+P313: If eye irritation persists: Get medical advice/attention.
12. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 5 - 9 Revision: 3 – Replaces : 2 Partiti on coefficient: n - octanol/water Vapour pressure Density (g/ml) Relative vapour density Particle characteristics Log Pow 3.242 @ 25 °C ( bis - [4 - (2,3 - epoxipropoxi)phenyl]propane ) Not known. 1.1 - 1.2 g/cm³ Not known. Not known. 9.2 Other information None. SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable under normal conditions. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of hazardous reactions No hazardous reactions known if used for its intended purpose. 10.4 Conditions to avoid None anticipated. 10.5 Incompatible materials Strong oxidising agents , Acids , Alkalis , Amines 10.6 Hazardous decomposition products No hazardous decomposition products known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity - Ingestion Low oral toxicity. bis - [4 - (2,3 - epoxipropoxi)phenyl]propane : LD50 (oral,rat) mg/kg: >2000 Acute toxicity - Skin Contact Low acute toxicity. Acute toxicity - Inhalation Low acute toxicity. Skin corrosion/irritation Causes skin irritation. No data. Serious eye damage/irritation Causes serious eye irritation. No data. Skin sensitization data May cause an allergic skin reac tion. No data. Respiratory sensitization data Not classified. Germ cell mutagenicity There is no evidence of mutagenic potential. Carcinogenicity No evidence of carcinogenic effects. Reproductive toxicity No evidence of reproductive effects. Lactation Not classified. STOT - single exposure None anticipated. STOT - repeated exposure None anticipated. Aspiration hazard Not classified. 11.2 Other information Not known. SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity Toxic to aquatic life with long lasting effects. Toxicity - Aquatic invertebrates bis - [4 - (2,3 - epoxipropoxi)phenyl]propane : EC50 Acute (Daphnia magna) (48 hour) : 2.7 mg/l NOEC Chronic (Daphnia magna) (21 days) : 0.3 mg/l Toxicity - Fish bis - [4 - (2,3 - epoxipropoxi)phenyl]propane : LC50 Acute (Rainbow trout) (96 hour) : 1.5 mg/l Toxicity - Algae bis - [4 - (2,3 - epoxipropoxi)phenyl]propane : EC50 Acute (Green algae) (72 hour) : 9.4 mg/l Toxicity - Sediment Compartment Not classified.
9. SAFETY DATA SHEET Dat e of Issue: 09 - 09 - 2020 Date of Revision: 12 - 06 - 2023 Gorilla Epoxy (Resin) Page: 2 - 9 Revision: 3 – Replaces : 2 Signal Word(s) Warning Hazard Statement(s) H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H411: Toxic to aquatic life with long lasting effects. Precautionary Statement(s) P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P261: Avoid breathing vapours. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P501: Dispose of contents in accordance with local, state or national legislation. 2.3 Other hazards None known. 2.4 Additional Information For full text of H/P Statements see section 16. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Not applicable. 3.2 Mixtures HAZARDOUS INGREDIENT(S) CAS No. EC No. / REACH Registration No. %W/W Hazard Statement(s) Ha zard Pictogram(s) bis - [4 - (2,3 - epoxipropoxi)phenyl]propane 1675 - 54 - 3 216 - 823 - 5 01 - 2119456619 - 26 - XXXX <99 Skin Irrit. 2 H315 Skin Sens. 1 H317 Eye Irrit. 2 H319 Aquatic Chronic 2 H411 GHS07 GHS09 [3 - (2,3 - epoxypropoxy)propyl]trimethoxy silane 2530 - 83 - 8 219 - 784 - 2 01 - 2119513212 - 58 - XXXX <2 Eye Dam. 1 H318 GHS05 1 - chloro - 2,3 - epoxypropane 106 - 89 - 8 203 - 439 - 8 01 - 2119457436 - 33 - XXXX <0.001 Flam. Liq. 3 H226 Acute Tox. 3 H301 Acute Tox. 3 H311 Skin Corr. 1B H314 Skin Sens. 1 H317 Acute Tox. 3 H331 Carc. 1B H350 GHS02 GHS06 GHS05 GHS08 GHS07 Methanol 67 - 56 - 1 200 - 659 - 6 01 - 2119433307 - 44 - XXXX <0.001 Flam. Liq. 2 H225 Acute Tox. 3 H301 Acute Tox. 3 H311 Acute Tox. 3 H331 STOT SE 1 H370 GHS02 GHS06 GHS08 bisphenol A 80 - 05 - 7 201 - 245 - 8 01 - 2119457856 - 23 - XXXX <0.001 Skin Sens. 1 H317 Eye Dam. 1 H318 STOT SE 3 H335 Repr. 1B H360F GHS05 GHS08 GHS07 SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures Inhalation If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
2. SAFETY DATA SHEET Date of Issue: 18 - 01 - 202 1 Date of Revision: 12 - 06 - 2 023 Gorilla Epoxy (Hardener) Page: 2 - 7 Revision: 3 – Replaces: 2 Signal Word(s) Danger Hazard Statement(s) H31 5 : Causes ski n irritation. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H412: Harmful to aqua tic life with long lasting effects. Precautionary Statement(s) P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P26 1 : Avoid breathing vapours. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P501: Dispose of contents in accordance with local, state or national legislation. 2.3 Other hazards None known. 2.4 Additional Information For full text of H/P Statements see section 16. Note Gorilla Epoxy contains 2,2,4(or 2,4,4) - trimethylhexane - 1,6 - diamine CAS No. 25513 - 64 - 8 which, according to Annex 1, Table 3.2.3 of CLP carries the H314: corrosive classification. Product level dermal corrosivity testing for Gorilla Epoxy confirms the product is classified as a skin irritant rather than corrosive. Positive results in a valid and acc epted skin corrosion test (Corrositex test) classifies the mixture as Non - corrosive utilizing multiple replicate samples indicating highly reproducible results. As a result, the health hazard and transport classification have been changed to reflect the Ep oxy results: UN Non - Corrosive and not a GHS Category 1. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Not applicable. 3.2 Mixtures HAZARDOUS INGREDIENT(S) CAS No. EC No. / REACH Registration No. %W/W Hazard Statement(s) Hazard Pictogram(s) Poly[oxy(methyl - 1,2 - ethanediyl)], α - hydro - ω - hydroxy - , ether with 2,2 - bis(hydroxymethyl) - 1,3 - propanediol (4:1), 2 - hydroxy - 3 - mercaptopropyl ether 72244 - 98 - 5 615 - 735 - 8 01 - 2120118957 - 46 - XXXX <85 Skin Sens. 1B H317 Aquatic Chronic 3 H412 GHS07 2,2,4(or 2,4,4) - trimethylhexane - 1,6 - diamine 25513 - 64 - 8 247 - 063 - 2 01 - 2119560598 - 25 - XXXX <20 Acute Tox. 4 H 302 Skin Corr. 1A H314 Skin Sens. 1A H317 Eye Dam. 1 H318 GHS05 GHS07 1,4 - diazabicyclooctane 280 - 57 - 9 205 - 999 - 9 01 - 2119980944 - 22 - XXXX <1 Flam. Sol. 1 H228 Acute Tox. 4 H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 GHS02 GHS05 GHS07 2,6 - di - tert - butyl - p - cresol 128 - 37 - 0 204 - 881 - 4 01 - 2119565113 - 46 - XXXX <0.5 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 GHS09 SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures Inhalation If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Skin Contact Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Ingestion Wash out mouth with water. If symptoms develop, obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Causes serious eye damage. Causes skin irritation. May cause an allergic skin reaction. 4.3 Indication of any immediate medical attention and special treatment needed