8. SA FE TY DATA SHEET Date of Issue : 0 2 - 12 - 2021 Date of Revision: 12 - 06 - 2023 G orilla Super Glue Liquid Page: 8 - 8 Revision: 9 - Replaces : 8 Ltd gives no warranty as to the fitness of the product for any particular purpo se an d any implied warranty or conditio n (statutory or otherwise) is excluded except to t he extent that ex clusion is prevented by la w. Gorilla Glue Europe Ltd accepts no liability for loss or damage (other than that arising from death or personal injury ca used by defective product, i f proved), resulting from reliance on this information. Freed om under Patents, Copyri ght and Designs can not be assumed.
6. SA FE TY DATA SHEET Date of Issue : 0 2 - 12 - 2021 Date of Revision: 12 - 06 - 2023 G orilla Super Glue Liquid Page: 6 - 8 Revision: 9 - Replaces : 8 14.3 Transport hazard class(es) Not applicable 14.4 Packing group Not appli cable 14.5 Environmental hazards Not classified as a Marine Po llutant. 14.6 Special precautions for us er Not known 14.7 Maritime t ransport in bulk accord ing to IMO instruments Not known SEC TION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental re gu lations/legislation specific for the subs tance or mixture European Regulations - Authorisations and/or Res trictions On Use Candidate Li st of Substan ces of Very High Concern for Authorisation Not listed REACH: ANNEX XIV list of substances subject to authorisa ti on Not listed REACH: Annex XVII Restrictions on the manufacture, pl acing on the market and use of cer tain dangerous substances, mixtures and articles e thyl 2 - cyanoacrylate (7085 - 8 5 - 0), tetrahy drofuran (109 - 99 - 9), 1,4 - dihydroxybenzene (1 23 - 31 - 9) Community Rolling Action Plan (CoRAP) tetrahy dro furan (1 09 - 99 - 9), Hydroquinone (123 - 31 - 9) R egulation (EU ) N° 2019/1021 of the European Parliament an d of the Council on persistent organic pollutants Not lis ted Regul at ion (EC) N° 1005/2009 on sub stances that deplete the ozone layer Not listed Regulation (EU ) N° 649/20 12 of the European Parliament and of the Council c on cerning the export and impor t of hazardou s chemicals Not listed Nat ional regulations Other Not kn own. 15.2 Chemical Safety Assessment A REACH c hemical saf ety assessment has not been carried out. SECTION 16: OTHER INFORMATION The foll owing sections contain revisions o r new statements: 2, 11, 16 LEG END Haz ard Pictogram(s) GHS07 GHS02: GHS: Flame GHS05: GHS: Corrosion GHS08: GHS: Health hazard GHS09: GHS: Environment Hazard c lassification Flam. Liq. 2 : Flammable l iquid , Category 2 Acute Tox. 4 : Acute toxi city , Cat e gory 4 Skin Irrit. 2 : Skin corrosion/irritation , Categ ory 2
1. SA FE TY DATA SHEET Date of Issue : 0 2 - 12 - 2021 Date of Revision: 12 - 06 - 2023 G orilla Super Glue Liquid Page: 1 - 8 Revision: 9 - Replaces : 8 ACCORDING TO EC - REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2020/878 SECTION 1: IDENTIFICATION OF THE SUB STANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product Name Gorilla Super Glue Liquid CA S No. Not applicable. EC No. Not applicable. REACH Registr at ion No. Not known. Unique Formula Identifier (UFI) H6NA - G09T - J00X - GF1E 1.2 Rele vant identified uses of the substance or mixture and uses advised agains t Identified Use(s) Adhesives. Uses Advised Against Not known. 1.3 Details of the supplier of the safety data sheet Manufacturer Company Identification Gorilla Glue Europe Ltd Address of Manufacturer 26 Eaton Avenue Matrix Park Buckshaw Village Chorley Lancashire Postal code PR7 7NA Telephone: 01257 241 319 Fax Not known. E - mail Eucustomercare@gorillaglue.com Offic e hours 08:30 - 17:00 Supplier Company Identification GG Bra nds Netherlands B.V. Address of Supplier Lichttoren 32 5611 BJ Eindhoven Telephone +31 85 064 4029 E - mail Eucustomercare@gorillaglue.com Offic e hours 08:30 - 17:00 1.4 Emergency telephone number Suppli er Contact : Stuart Shotton Emergency Phone No. +44 (0)843 507 1200 Northern Ire land: NHS Direct Emer genc y Phone No. Republic o f Ireland : Emergenc y Phone No. +44 111 (24 hours) NPIC Irela nd +353 ( 0) 1 809 2166 (8am - 10pm) SECTION 2 : HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Regulation (EC) No. 1272/2008 (CLP ) Skin Irrit. 2 : Causes skin irritation. Eye Irrit. 2 : Causes seri ous eye irritation. STOT SE 3 : May cause respiratory irritation. 2.2 Label elements Ac cording to Regulation (EC) No. 1272/2008 (CLP) Product Name Gorilla Super Glue Liquid Hazard Pictogram(s) GHS07 Signal Word(s) Warning H azard Statement(s) H315: Caus es skin irritation. H319: Causes serious eye irritation. H335: May cause respirato ry irritation. EUH202: Cya noacryla te. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
4. SA FE TY DATA SHEET Date of Issue : 0 2 - 12 - 2021 Date of Revision: 12 - 06 - 2023 G orilla Super Glue Liquid Page: 4 - 8 Revision: 9 - Replaces : 8 Skin protection We ar suitable protective clothing and gloves. Breakthrough time of the glove material: refer to the information provided by the gloves’ producer. Respira to ry protection In case of inadeq uate ventilation wear respiratory protection. A suitable mask with filter type A may be appropriate. Therma l hazards Not ap plicable. 8.2.3. Environm ental Exposure Controls Do not relea se large quantities into the surfa ce water or into drains. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 I nf ormation on basic physical and c hemical pro perties Physical state Liquid. Colour Transparent. Odour Characteristic. Melting point/freezing point Not known. Boiling point or initial boiling point and boiling range Not known. Flammability N ot known. Lower and upper explosion limit Not known. Flash Po in t 81 °C Auto - ignition temperature Not known. Decomposition Tem pe rature Not known. pH N ot known. Kinematic Viscosity Not known. Solubility Solubility ( Water) : Immiscible. Solu bility (Oth er) : Not known. Partition coeff icient n - octanol /water (log value) Not known. Vapour pressure Not known. De nsity and/or relative density Density (g/ml) : 1.06 g /cm³ @ 20 °C Relative vapour density Not known. Particle characteristics Not known. 9.2 Oth er information Organic solv ents 0 .3% SE CTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable under normal conditions. 10.2 Chemical Stab ility Stable under normal condition s. 10.3 Possibility of hazardous reactions No hazardous reactions known if used for its intended purpose. 10.4 Conditions to avoid Heat and direct sunlight. 10.5 Incompatible m aterials Not known. 10.6 H a zardous decomposition products No hazardous decomp osition products known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on hazard classes as defined in R egulation (EC) No 1272/2008 Acute toxicity - Inges tion Lo w oral toxicity. Calculation method : Calculated acute toxicity estimate ( ATE ) Calc ATE -
3. SA FE TY DATA SHEET Date of Issue : 0 2 - 12 - 2021 Date of Revision: 12 - 06 - 2023 G orilla Super Glue Liquid Page: 3 - 8 Revision: 9 - Replaces : 8 Unsuitable ext inguishing media None. 5.2 Special hazards arising from the substance or m ixture Decomposes in a fire giving o ff toxic fumes: Carbon monoxide , Nitrogen oxides , isocyanates , trace s of hydrogen cyanide . 5.3 Advice for firefighters Fire fighters sho uld wear co mplete protective clothing including self - contained breathing apparatus. SECT ION 6: ACCIDENTAL RELEASE MEASURES 6 . 1 Personal precautions, protective equipment and emergency proc edures Provi de adequate ventilation. Avoid breat h ing vapours. Wear appropriate personal protective equipment, av oid direct contact. Take off contaminated clothing and wash it before reuse. Wash hands and e xposed skin thoroughly after handling. 6.2 Environ mental precautions Do not release large quantities into the surface water or into drains. 6.3 Methods and material for containme nt and cleaning up Adsorb spillages onto sand, earth or any suitable adsorbent material. Trans fer to a container for disposal. 6.4 Referenc e to other sections See Also Section 8, 13. SEC TION 7: HANDLING AND STORAGE 7.1 Precaution s for safe handling If medical advi c e is needed, have product contai ner or labe l at hand. Cyanoacryl ate. Danger. Bonds skin and ey es in seconds. Keep out of the reach of children. Use only outdoors o r in a well - ventilated area. Wear protective gloves/protective c lothing/eye protection/face pr otection. Avoid breathing vapours. Avoid contact with s kin and eye s. Wash hands and expo sed skin thoroughly after hand ling. 7.2 Conditions for safe storage, includi ng any incompat i bilities Store in a well - ventilated place. Keep container tightly closed. Store locked up. Storage t emperature Ambient. Storage life Stable under normal conditions. Inco mpatible ma terials None known. 7.3 Specif ic end use(s) Adhesives. SEC TION 8: EXPOSURE CONTRO LS/PERSONAL PROTECTION 8.1 Control parameters 8.1.1 Occupational Exposure Limi ts SUB STANCE. CAS No. LTEL (8 hr TWA ppm) LTEL (8 hr TWA mg/m³) STEL (ppm) STEL (mg/m³) Note Ethyl cyan oacrylate 7085 - 85 - 0 0.3 1.5 Tetrahydrofuran 109 - 99 - 9 50 150 100 300 Sk Hydroquinone 123 - 31 - 9 0.5 Regio n Source United Kingdom UK Workpl ace Exposur e Limits EH40/2005 (Fourth edition, published 2020) Remark Notes Sk Can be absorbed through th e skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemi c toxicity. 8.2 Exposure cont rols 8.2.1. Appropriate engineering contro ls Ensure adequate ventilation. A washing facility/water for eye a nd skin cleaning purposes should be present. 8.2.2. Personal protection equipment Eye Protection Wear p rotective eyewear (goggles, face shield, or safety glasses).
5. SA FE TY DATA SHEET Date of Issue : 0 2 - 12 - 2021 Date of Revision: 12 - 06 - 2023 G orilla Super Glue Liquid Page: 5 - 8 Revision: 9 - Replaces : 8 125000.00000 Acute toxicity - Skin Contact Low acute toxicity. Acute toxicit y - Inhalation Lo w acute toxicity. Skin corrosio n/irritation Cause s skin irri t ation. No data. Serious eye damag e/irritation Causes serious eye irr it ation. No data. Skin sensitization data Contains: 1, 4 - dih yd roxybenzene . May produce an allergic r eaction. No data. Respiratory sensitization data Not classifie d. Germ cell mutagenicity There is no evide nce of mutagenic potential. Car ci nogenicity No evidence of carcinogeni c effects. Reproductive toxicity No evidence of reproductive effects. Lactation Not classified. STO T - single exposure May cause respi ra tory irritation. No data. STOT - repeated exposure None anticipated. Aspiration hazard Not c lassifie d. 11.2 Information on other hazards 11.2 .1 Endocrine disrupting properties 11.2 . 2 Other hazards None known. None known. SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity - Aquatic i nvertebrates Low toxicity to invertebra tes. Toxici ty - Fish Low to xicity to fish . Toxicity - Algae Low toxicity to algae. Toxicity - S ediment Compartment Not classified. Toxicity - Terrestrial Compartment Not classified. 12.2 Persistenc e and degradability No information av ailable. 12.3 Bioaccumulative potential No information available. 12. 4 Mobility in soil Immiscible wit h water. The product is predicted to have low mobility in soil. 12.5 Results of PBT and vPvB assessment Not classified as PBT or vPvB. 12.6 Endocrine disrupting properties None known. 12.7 Other ad verse effects Not known. SECTION 13: DISPOSAL CONSID ERATIONS 13.1 Was te treatment methods Dispose of this material and its container as hazardous waste. Do not dispose of with househo ld waste. Incineration by an approved me thod could be considered. 13 .2 Additional Information Disposal should be in ac cordance with local, state or national legi slation. 08 00 00 WASTES FORM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU ) OF COATINGS (PAINTS, VARNISHES A ND VITREOUS ENAMELS,) ADHESIVES, SEALANTS AND PR IN TING INKS 08 04 00 wastes from MFS U of adhesives and sealants (incl uding waterproofing products) 08 04 09 wa ste adhesives and sealants containing organic so lv ents or other dangerous sub stances SECTION 14: TRANSPORT INFORMATION Not classified as hazardous for transpo rt. 14.1 UN number or ID number Not applicable 14.2 UN proper ship ping name Not applicable
7. SA FE TY DATA SHEET Date of Issue : 0 2 - 12 - 2021 Date of Revision: 12 - 06 - 2023 G orilla Super Glue Liquid Page: 7 - 8 Revision: 9 - Replaces : 8 Skin Sens. 1 : Skin sensitization , Category 1 Eye Dam. 1 : Serious eye damage/irritation , Catego ry 1 Eye I rrit. 2 : Serious eye damage/irritatio n , Category 2 STOT SE 3 : Specific target or gan toxicity — single exposure , Category 3 Muta. 2 : Germ cell mutagenic it y , Category 2 Carc. 2 : Carcinogenicity , Category 2 Aquatic Acute 1 : Hazardous to the aquatic environment , A cute , Category 1 Hazard Statement(s) H22 5: Highly flammable liquid and va pour. H302: Harmful if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H319: Causes serious eye irritation. H335: May cause respiratory irritati on. H3 41: Suspected of causing gen et ic defects. H351: Suspected of causing cancer. H400: Very toxic to aq uatic life. EUH202 : Cyanoacry late. Danger. Bonds skin and eyes in seconds. Keep o ut of the reach of children. Precautionary Statement(s) P101: If medical advice is needed, have product co ntainer or lab el at hand. P261: Avoid bre at hing vapours. P264: Wash hands and exposed skin thoroughly after handling. P271: Use only outdoors or in a we ll - ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection. P302+P352: IF ON SKIN: Wash with plenty of wate r. P304+P340: IF INHALED: Remov e person to fresh air a nd keep com fortable for b reathing. P305+P351+P338: I F IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsi ng. P312: Call a POISON CENTRE/doctor i f you feel unwell. P332+P313: If skin irritation occur s: Get medic al adv ice/attention. P3 37+P313: If eye ir ritation persists: Get medical advice/attention. P36 2+P364: Take off co ntaminated clothing and wash it be fore reuse. P403+P233: Store in a well - ven tilated place. Ke ep container tightly closed. P405: St ore locked up. P501: Dispose o f contents in ac cor dance with local, state or national legislation. Acronyms A TE : Acute Toxici ty Estimate CAS : Chemical Abstracts Service CLP : Reg ul ation (EC) No 1272/200 8 on classification , labelling and packaging of substances and mixtures DNEL : De rived No Effect Level E C : European Community EINECS : European Inventory of Existing Commercial Chemica l Substances LTEL : Long term exposure limit PBT : Per si stent, Bioaccu mulative and Toxic PNEC : Predicted No Effect Con centra tion REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals STEL : Short term exposure limit STOT : Specific Target Organ Toxicity vPvB : very Persistent and very Bioaccu mu lative Key literature references and sources for data u sed to compile the SDS Regulation (EC ) No. 1272/ 2008 (CLP) Di sclaime rs Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good fai th, but it is for the Users to satisfy themselves of the suitabilit y of th e product for their own particular purpose. Gorilla Glue Europe
2. SA FE TY DATA SHEET Date of Issue : 0 2 - 12 - 2021 Date of Revision: 12 - 06 - 2023 G orilla Super Glue Liquid Page: 2 - 8 Revision: 9 - Replaces : 8 EU H20 8: Conta ins: (1,4 - dihydroxybenzene) May produce an allergic reaction. Precautionary Statement(s) P101: If me dic al advice is needed, have product conta iner or label at hand. P261: Avoid breathing vapours. P280: Wear protective gloves/protective clothing/eye protectio n/f ace prote ction. P305+P351+P338: IF IN EYES: Rinse cautiously with water fo r several minutes. Remove contac t lenses, i f present and easy to do. Continue rinsing. P337+P313: If eye irritation persists : Get medical advice/attention. P5 01: Dispose of contents in accordance with local, state or national legislation. 2.3 Other hazards None kn own. 2.4 Additional Information For full text of H/P Statements see sec tion 16. SECTION 3: COMPOSITIO N/INFORMATION ON INGREDIENTS 3.1 Su bstances Not applicable. 3.2 Mixtures HAZARDOUS INGREDIENT(S) C AS No. EC No. / REACH Regi stration No. %W/W Hazard Statement(s) H azard Pictogram(s) ethyl 2 - cyanoacrylate 7085 - 85 - 0 230 - 391 - 5 01 - 2119527766 - 29 - XXXX 80 - 90 Skin Irrit. 2 H315 Eye Irrit. 2 H319 STOT SE 3 H335 GHS07 te trahydrofur an 109 - 99 - 9 203 - 726 - 8 01 - 2119444314 - 46 - XXXX <0.5 Flam. Liq. 2 H225 Eye Irrit. 2 H319 S TOT SE 3 H335 Carc. 2 H351 GHS02 GHS08 G HS07 1,4 - dihydroxybenzene 123 - 31 - 9 204 - 617 - 8 01 - 2119527766 - 29 - XXXX <0.5 A cute Tox. 4 H302 Skin Sens. 1 H317 Eye Dam. 1 H318 Muta. 2 H341 Carc. 2 H351 Aqu atic Acute 1 H400 GHS05 GHS08 GHS07 GHS09 HAZARDOUS INGREDIENT(S) CAS No. Specific Concentration Limit M - fa ctor ATE ethyl 2 - cyanoacr ylate 708 5 - 85 - 0 STOT SE 3 C>= 10.00 <= 100.00 tetrahydrofuran 109 - 99 - 9 Eye Irrit. 2 C>= 25.00 <= 100. 00 STOT SE 3 C>= 25.00 <= 100.00 1,4 - dihyd roxybenzene 123 - 31 - 9 Aquatic Acute 1: 10 Acute Tox. 4 (H302) : 500 Contains no non - classified vPvB subs tances. Contains no non - classified substances with a Union workplace exposure limit. For full text of H/P Statements see section 16. SECTION 4: FIRST AID MEASURES 4.1 Description of first ai d measures Inhalation Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTRE /doctor if you feel unwell. Skin Conta ct Wash with plenty of water. If skin irrita tion occurs: Get medical advice/ attention. Eye Contact Rinse cautiously with w ater for several minutes. Remove conta ct lenses, if present and easy t o do. Conti nue rinsing. If eye irritati on persists: Get medical advice/attention. Ing estion Wash out mouth with water. 4.2 Most importa nt symptoms and effects , both acute and delayed Causes irrit ation to eyes and skin. May cause respiratory irritation. 4.3 Indication of any immediate medical attention and special treatment needed Unlik ely to be r equired but if necessary treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing me dia Suitable Extinguishing media As appropr iate for surrounding fire. Extinguish w ith carbon dioxide, dry chemical , foam o r w aterspray.